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Preheat oven to 175°C. Prepare a muffin tin by oiling or lining up with paper moulds. Melt butter on medium heat, let it cool.
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Whisk together flour, baking powder, baking soda, salt and sugar. In another bowl mix egg, vanilla and milk.
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Combine dry ingredients with milk-egg mix and the warm butter. Mix until a shiny dough comes out. Pour into prepared moulds and bake for about 25 minutes or a toothpick insert comes out clean. Let them cool on a wire rack
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For the frosting. Sift the confectioners sugar and combine with espresso and then with mascarpone and cream cheese. Decorate cupcakes as you like.